Lucy-Alamo Projects - Hydroxyl Generation and Atmospheric Methane Destruction

As you know the weather is starting to change rapidly for the worse now and I have been working on Arctic methane induced global warming for about 14 years. There are massive deposits of methane gas trapped in the undersea permafrosts in Russian waters and onland in Siberia as well and if the global warming boils of just 10% of what is there, there is enough to cause a Permian style extinction event that humanity will not survive. Some brilliant work on the Arctic methane threat has been done by a Russian scientist Natalia Shakhova and others who indicate that we are in a very perilous position, if we don't find a way of reducing the atmospheric methane and depressurizing the undersea methane to stop the massive methane eruptions there. I and some other workers have designed a radio-laser Atmospheric methane destruction system based on the early Russian radio-wave induced conversion of methane to nano-diamonds. This radio-laser system can be installed on nuclear powered boats such as the 40 Russian Arctic ice breakers and start immediate work on destroying the atmospheric methane clouds that are building up in the Arctic. An abstract about the system is attached and it has been accepted for presentation at a congress of the American Meteorological Society to be held on January 10 - 14, 2016 at New Orleans in Louisiana, U.S.A. This system should be mounted on the nuclear icebreakers and used onshore. Once the methane is brought under control there should be a reduction in the massive fire hazards, heat waves and severe storms systems that are plaguing Russia and the rest of the world.

Yours sincerely,

Malcolm P.R. Light
Earth Scientist

The Abstract follows:-
No. 275345 Lucy - Alamo Projects - Hydroxyl Generation and Atmospheric Methane Destruction.
by
Malcolm P.R. Light (Dr)
Retired, Cortegana, Spain

Congress of the American Meteorological Society, Wednesday 13, January, 2016

Methane formed by organisms in the water becomes trapped in the fabric of water ice crystals when it freezes and is stable below about 300 metres depth in the Arctic Ocean and on the shallow East Siberian Arctic Shelf. There are such massive methane reserves below the Arctic Ocean floor, that they represent 100 times the amount, that is required to cause a Permian style major extinction event, should the subsea Arctic methane be released into the atmosphere because of methane's giant global warming potential (100 to 1000 times CO2) over a short time period (Light and Solana, 2012 - 2014, Carana 2012 - 2014). There are also giant reservoirs of mantle methane, originally sealed in by shallow methane hydrate plugs in fractures cutting the Arctic seafloor and onshore in N. Siberia (Light, 2014, Carana 2013, Light, Hensel and Carana, 2015). The whole northern hemisphere is now covered by a thickening atmospheric methane global warming veil from Arctic methane emissions at the level of the jet streams, which is spreading southwards at about 1 km a day and already totally envelopes the United States (Figure 1). There must therefore be a world-wide effort to capture and thus depressurise the methane in the subsea and surface Arctic permafrost and eradicate the quantities accumulating in the ocean and atmosphere.

Methane produced at the surface diffuses upward and is broken down by photo dissociation (sunlight) and chemical attack by nascent oxygen and hydroxyl (Heicklen, 1967). The Lucy Project is a radio/laser system for destroying the first hydrogen bond in atmospheric methane when it forms dangerously thick global warming clouds over the Arctic (Figure 2, Light & Carana, 2012). It generates similar gas products to those normally produced by the natural destruction of methane in the atmosphere over some 15 to 20 years. Radio frequencies are used in generating nano-diamonds from methane gas in commercial applications over the entire pressure range of the atmosphere up to 50 km altitude (Figure 2, Light and Carana, 2012). Recent experiments have shown that when a test tube of seawater was illuminated by a polarized 13.56 MHZ radio beam, that flammable gases (nascent hydrogen and hydroxyls) were released at the top of the tube (iopscience.iop.org, 2013). In the Arctic Ocean, polarized 13.56 MHZ radio waves will decompose atmospheric humidity, mist, fog, ocean spray and the surface of the waves themselves into nascent hydrogen and hydroxyl over the region where a massive methane torch (plume) is entering the atmosphere, so that the additional hydroxyl produced will react with the rising methane, breaking a large part of it down (Figure 2)(iopscience.iop.org, 2013).

A better system could use Nd: glass heating lasers containing hexagonal neodymium which is stable below 863oC (Krupke 1986 in Lide and Frederickse, 1995). Neodymium glass lasers have extreme output parameters with peak powers near 10 to the power 14 watts when collimated and peak power densities of 10 to the power 18 watts per square cm if focused (Krupke 1986 in Lide and Frederickse, 1995). Velard (2006) states that at the Lawrence Livermore Laboratory, for inertial confinement nuclear fusion, "192 beams of Nd: glass - plate amplifier chains are being used in parallel clusters to generate very high energy (10 kilojoules) at a very high power (>10 power 12 watts) and at the second and third harmonics of the fundamental, with flexible pulse shapes and with sophisticated spectral and spacial on - target laser light qualities". The Nd: glass laser system is more stable and efficient than the longer wavelength CO lasers and shorter wavelength KrF lasers (Velard, 2006).

The three 13.56 MHZ radio transmitters in the Lucy Project (Figure 2) could be replaced by 3 groups of parallel lasers each forming a giant circular flash lamp. Half the Nd: glass lasers in the flash lamp could be tuned to exactly 21 million times the 13.56 MHZ methane destruction/nano-diamond formation frequency (Mitura, 1976). The adjacent alternate lasers will be tuned to a slightly different frequency exactly out of phase with the primary frequency by 13.56 MHZ.The Nd: glass lasers have a wavelength of 1052 nm equivalent to a frequency of 2.85*10 power 8 MHZ. The methane molecule requires 435 kilo-joules per mole to dislodge the first hydrogen proton and an average of 409.3 kilo - joules per mole for the other three protons (Hutchinson, 2014). Hydroxyl requires 493 kilo - joules per mole to generate it from water (Hutchinson, 2014). A set of four focused Nd; glass lasers will have an energy of about 454.5 kilo-joules per mole, and will be strong enough to dislodge the first hydrogen proton from a methane molecule. Of course this can also be achieved by increasing the number of focused lasers to six or eight. Exactly the same neodymium laser system could be shone on the sea surface, at the base of the rising methane cloud, generating hydroxyls and nascent oxygen and thus breaking down the methane. The power source for these radio transmitters/lasers in the Arctic can come from floating or coastal nuclear or gas electric power stations and the transmitters could be located on shore or on boats, submarines, oil-rigs and aircraft. We have only 1 to 5 years to get an efficient methane destruction radio-laser system designed, tested and installed (Lucy and Alamo (HAARP) projects) before the accelerating methane eruptions take us into uncontrollable runaway global warming. Humanity will then be looking at catastrophic storm systems, a fast rate of sea level rise and coastal zone flooding with its disastrous effects on world populations and global stability.

Links

- Lucy-Alamo Projects - Hydroxyl Generation and Atmospheric Methane Destruction, by Malcolm P.R. Light (Dr) Light
https://ams.confex.com/ams/96Annual/webprogram/Paper275345.html

- North Siberian Arctic Permafrost Methane Eruption Vents, by Malcolm P.R. Light, Harold H. Hensel and Sam Carana 

http://arctic-news.blogspot.com/2015/04/north-siberian-arctic-permafrost-methane-eruption-vents.html

- WARNING - Planetary Omnicide between 2023 and 2031 

http://arctic-news.blogspot.com/2015/02/warning-planetary-omnicide-between-2023-and-2031.html
and 

https://www.facebook.com/photo.php?fbid=10155073267455161&set=a.10150592349770161.675455.655795160&type=3

- Poster created for Geophysical Congress on methane hydrates, earthquakes and global warming, Nice, France, 2002, by Malcolm Light and Carmen Solana
http://arctic-news.blogspot.com/p/seismic-activity.html

Poster Presentation at American Meteorological Society's 18th Conference on Atmospheric Chemistry, January 10 - 14,...
Posted by Sam Carana on Monday, October 19, 2015

Why are methane levels over the Arctic Ocean high from October to March?

Water temperatures at different depth

Why are methane concentrations in the atmosphere over the Arctic Ocean so high from October through to March?

The image below, replotted by Leonid Yurganov from a study by Chepurin et al, shows sea water temperature at different depths in the Barents Sea.

Above image illustrates that, while Arctic sea water at the surface reaches its highest temperatures in the months from July to September, water at greater depth reaches its highest temperature in the months from October to March. Accordingly, huge amounts of methane are starting to get released from the Arctic Ocean's seafloor in October.

Surface temperatures in October

As the image below shows, temperature at 2 meters was below 0°C (32°F, i.e. the temperature at which water freezes) over most of the Arctic Ocean on October 26, 2014. The Arctic was over 6°F (3.34°C) warmer than average, and at places was up to 20°C (36°F) warmer than average.

  

Image from 'Ocean temperature rise'

At the same time, continents around the Arctic Ocean are frozen. Surface temperatures over the Arctic Ocean were higher than temperatures on land at the end of October, due to the enormous amounts of heat being transferred from the waters of the Arctic Ocean to the atmosphere. This was the result of ocean heat content, which in 2014 was the highest on record, especially in the Arctic Ocean, which also made that at that time of year the sea ice extent was still minimal in extent and especially in volume. 

Start of freezing period

In October, the Arctic Ocean typically freezes over, so less heat will from then on be able to escape to the atmosphere. Sealed off from the atmosphere by sea ice, greater mixing of heat in the water will occur down to the seafloor of the Arctic Ocean.

Less fresh water added to Arctic Ocean

The sea ice also seals the water of the Arctic Ocean off from precipitation, so no more fresh water will be added to the Arctic Ocean due to rain falling or snow melting on the water. In October, temperatures on land around the Arctic Ocean will have fallen below freezing point, so less fresh water will flow from glaciers and rivers into the Arctic Ocean. At that time of year, melting of sea ice has also stopped, so fresh water from melting sea ice is no longer added to the Arctic Ocean either. 

Rising salt content

As addition of fresh water ends, the salt content of the water in the Arctic Ocean starts to rise accordingly, while the Gulf Stream continues to push salty water into the Arctic Ocean. The higher salt content of the water makes it easier for ice to melt at the seafloor of the Arctic Ocean. Saltier water causes ice in cracks and passages in sediments at the seafloor of the Arctic Ocean to melt, allowing methane contained in the sediment to escape. 

Pingos and conduits. Hovland et al. (2006)

The image on the right, from a study by Hovland et al., shows that hydrates can exist at the end of conduits in the sediment, formed when methane did escape from such hydrates in the past. Heat can travel down such conduits relatively fast, warming up the hydrates and destabilizing them in the process, which can result in huge abrupt releases of methane.

Heat can penetrate cracks and conduits in the seafloor, destabilizing methane held in hydrates and in the form of free gas in the sediments.

Less hydroxyl in atmosphere

Besides heat, open water also transfers more moisture to the air. The greater presence of sea ice from October onward acts as a seal, making that less moisture will evaporate from the water. Less moisture evaporating, together with the change of seasons (i.e. less sunshine) results in lower hydroxyl levels in the atmosphere at the higher latitudes of the Northern Hemisphere, in turn resulting in less methane being broken down in the atmosphere over the Arctic.

Gulf Stream

Malcolm Light writes in this and this earlier posts that the volume transport of the Gulf Stream has increased by three times since the 1940's, due to the rising atmospheric pressure difference set up between the polluted, greenhouse gas rich air above North America and the marine Atlantic Air. 

The increasingly heated Gulf Stream with its associated high winds and energy rich weather systems then flows NE to Europe where it is increasingly pummeling Great Britain with catastrophic storms, as also described in this earlier post, which adds that faster winds means more water evaporation, and warmer air holds more water vapor, so this can result in huge rainstorms that can rapidly devastate the integrity of the ice. The image below further illustrates the danger of strong winds over the North Atlantic reaching the Arctic.

Branches of the Gulf Stream then enter the Arctic and disassociate the subsea Arctic methane hydrate seals on subsea and deep high - pressure mantle methane reservoirs below the Eurasian Basin - Laptev Sea transition. This is releasing increasing amounts of methane into the atmosphere where they contribute to anomalously high local temperatures, greater than 20°C above average.

From: The Biggest Story of 2013

Emissions from North America are - due to the Coriolis effect - moving over areas off the North American coast in the path of the Gulf Stream (see animation on the right).

The Gulf Stream reaches its maximum temperatures off the North American coast in July. It can take almost four months for this heat to travel along the Gulf Coast and reach the Arctic Ocean, i.e. water warmed up off Florida in early July may only reach waters beyond Svalbard by the end of October.

Waters close to Svalbard reached temperatures as high as 63.5°F (17.5°C) on September 1, 2014 (green circle). The image below shows sea surface temperatures only - at greater depths (say about 300 m), the Gulf Stream can push even warmer water through the Greenland Sea than temperatures at the sea surface.

Since the passage west of Svalbard is rather shallow, a lot of this very warm water comes to the surface at that spot, resulting in an anomaly of 11.9°C. The high sea surface temperatures west of Svalbard thus show that the Gulf Stream can carry very warm water (warmer than 17°C) at greater depths and is pushing this underneath the sea ice north of Svalbard.

from: Causes of high methane levels over Arctic Ocean 

Through to March the following year, salty and warm water (i.e. warmer than water that is present in the Arctic Ocean) will continue to be carried by the Gulf Stream into the Arctic Ocean, while the sea ice will keep the water sealed off from the atmosphere, so little heat and moisture will be able to be transferred to the atmosphere. 

Start of melting period

This situation continues until March, when the sea ice starts to retreat and more hydroxyl starts getting produced in the atmosphere. Increased sea ice melt and glaciers melt, the latter resulting in warmer water flowing into the Arctic Ocean from rivers, will cause salinity levels in the Arctic Ocean to fall, in turn causing methane levels to fall in the atmosphere over the Arctic Ocean. Furthermore, the water traveling along the Gulf Stream and arriving in the Arctic Ocean in March will be relatively cold.  

References


- Chepurin, G.A., and J.A. Carton, 2012: Sub-arctic and Arctic sea surface temperature and its relation to ocean heat content 1982-2010, J. Geophys. Res.-Oceans., 117, C06019, DOI: 10.1029/2011JC007770. http://onlinelibrary.wiley.com/doi/10.1029/2011JC007770/abstract 

- Combination image created by Sam Carana with Climate Reanalyzer, from: Temperature Rise, http://arctic-news.blogspot.com/2014/10/ocean-temperature-rise.html 

- Submarine pingoes: Indicators of shallow gas hydrates in a pockmark at Nyegga, Norwegian Sea, by Martin Hovland and Henrik Svensen (2006) http://www.sciencedirect.com/science/article/pii/S0025322705003968

- Sea surface temperature west of Svalbard,
created by Sam Carana with
http://earth.nullschool.net

Post by Sam Carana.

Like a giant elevator to the stratosphere

Recent research results show that an atmospheric hole over the tropical West Pacific is reinforcing ozone depletion in the polar regions and could have a significant influence on the climate of the Earth.

Potsdam, 3 April 2014. An international team of researchers headed by Potsdam scientist Dr. Markus Rex from the Alfred Wegener Institute has discovered a previously unknown atmospheric phenomenon over the South Seas. Over the tropical West Pacific there is a natural, invisible hole extending over several thousand kilometres in a layer that prevents transport of most of the natural and manmade substances into the stratosphere by virtue of its chemical composition. Like in a giant elevator, many chemical compounds emitted at the ground pass thus unfiltered through this so-called “detergent layer” of the atmosphere. Scientists call it the “OH shield”. The newly discovered phenomenon over the South Seas boosts ozone depletion in the polar regions and could have a significant influence on the future climate of the Earth – also because of rising air pollution in South East Asia.

In tropical thunderstorms over the West Pacific air masses and
the chemical substances they contain are quickly hurled upward
to the edge of the stratosphere. If there are sufficient OH
molecules in the atmosphere, the air is extensively cleaned by
chemical transformation processes. Where OH concentrations are
low, such as those now found in large sections of the tropical
West Pacific, the cleaning capacity of the atmosphere is reduced.
Photo: Markus Rex, Alfred Wegener Institute

At first Dr. Markus Rex suspected a series of flawed measurements. In October 2009 the atmospheric physicist from the Alfred Wegener Institute, Helmholtz Centre for Polar and Marine Research (AWI) was on board the German research vessel “Sonne” to measure trace substances in the atmosphere in the tropical West Pacific.

Tried and tested a thousand times over, the ozone probes he sent up into the tropical sky with a research balloon every 400 kilometres reported – nothing.

Or to be more accurate: almost nothing. The ozone concentrations in his measurements remained nearly constantly below the detection limit of approx. 10 ppbv* in the entire vertical range from the surface of the Earth to an altitude of around 15 kilometres. Normally ozone concentrations in this part of the atmosphere are three to ten times higher.

Although low values at an altitude of around 15 kilometres were known from earlier measurements in the peripheral area of the tropical West Pacific, the complete absence of ozone at all heights was surprising. However, after a short period of doubt and various tests of the instruments it dawned on the worldwide recognised ozone specialist that he might be onto a phenomenon yet unknown to science. A few research years later and after the involvement of other colleagues came confirmation: Markus Rex and his team on board the “Sonne” had tracked down a giant natural hole over the tropical South Seas, situated in a special layer of the lower atmosphere known as the “OH shield”. The research results on the newly discovered OH minimum will be published soon in the journal “Atmospheric Chemistry and Physics”, with the Institute of Environmental Physics of the University of Bremen and other international research institutions as partners.

Nearly all chemical substances produced by people, animals,
plants, algae or microorganisms on the ground or in the oceans
react quickly with OH and break down in this process. During this
chemical self-cleaning process substances that are not easily
water-soluble are transformed into water-soluble products and
then washed out by precipitation. Through this mechanism OH
molecules remove most substances from the atmosphere.
The OH molecule is therefore also called the detergent of the
atmosphere. Only extremely long-lived chemical compounds,
such as methane or CFCs, also known as "ozone killers", can
rise through the OH shield into the stratosphere.
Graphics: Markus Rex, Alfred Wegener Institute

“Even though the sky appears to be an extensively uniform space for most people, it is composed of chemically and physically very different layers,” Markus Rex explains the complex makeup of the atmosphere.

The air layers near the ground contain hundreds or even thousands of chemical compounds. This is why winter and spring, mountains and sea, city and forests all have a distinct smell. The great majority of these substances are broken down into water-soluble compounds in the lower kilometres of the atmosphere and are subsequently washed out by rain.

Since these processes require the presence of a certain chemical substance, the so called hydroxyl (=OH) radical, this part of the atmosphere is called the “OH shield”. It acts like a huge atmospheric washing machine in which OH is the detergent.

The OH shield is part of the troposphere, as the lower part of the atmosphere is called. “Only a few, extremely long-lived compounds manage to make their way through the OH shield,” says Rex, “then they also get through the tropopause and enter the stratosphere.” Tropopause refers to the boundary layer between the troposphere and the next atmospheric layer above it, the stratosphere. Particularly substances that enter the stratosphere unfold a global impact. The reason for this is that once they have reached the stratosphere, their degradation products remain up there for many years and spread over the entire globe.

Extremely long-lived chemical compounds find their way to the stratosphere, even where the OH shield is intact. These include methane, nitrous oxide (“laughing gas”), halons, methyl bromide and chlorofluorocarbons (CFCs), which are notorious as “ozone killers” because they play a major role in ozone depletion in the polar regions.

Location and extent of low ozone concentrations and thus
of the OH hole over the West Pacific. Fig. (a) shows the
region of origin of the air in the stratosphere, Fig. (b) ozone
sonde measurements (dots) and satellite measurements
(coloured map) of the total amount of ozone in the
tropospheric column of air and Fig. (c) the total amount of
OH in the tropospheric column of air calculated with a model.
Graphics: Markus Rex, Alfred Wegener Institute.

After many years of research scientists now understand the complicated process of stratospheric ozone depletion very well.

“Nevertheless measured ozone depletion rates were often quite a bit larger than theoretically calculated in our models,” Markus Rex points out a long unsolved problem of atmospheric research.

“Through the discovery of the OH hole over the tropical West Pacific we have now presumably made a contribution to solving this puzzle.”

And at the same time discovered a phenomenon that raises a number of new questions for climate policy.

Researchers are now tackling these questions in a new research project funded by the EU with around 9 million euros, i.e. “StratoClim”, which is coordinated by the Alfred Wegener Institute. Within this project a new monitoring station will be established in the tropical Westpacific, together with the Institute of Environmental Physics at the University of Bremen.

“We have to realise,” reminds the Potsdam atmospheric physicist, “that chemical compounds which enter the stratosphere always have a global impact.” Thanks to the OH hole that the researchers discovered over the tropical Pacific, greater amounts of brominated hydrocarbons can reach the stratosphere than in other parts of the world. Although their ascent takes place over the tropical West Pacific, these compounds amplify ozone depletion in the polar regions. Since scientists identified this phenomenon and took it into account in the modelling of stratospheric ozone depletion, their models have corresponded excellently with the actually measured data.

However, it is not only brominated hydrocarbons that enter the stratosphere over the tropical West Pacific. “You can imagine this region as a giant elevator to the stratosphere,” states Markus Rex using an apt comparison. Other substances, too, rise here to a yet unknown extent while they are intercepted to a larger extent in the OH shield elsewhere on the globe. One example is sulphur dioxide, which has a significant impact on the climate.

Sulphur particles in the stratosphere reflect sunlight and therefore act antagonistically to atmospheric greenhouse gases like CO2, which capture the heat of the sun on the Earth. To put it simply, whereas greenhouse gases in the atmosphere heat the globe, sulphur particles in the stratosphere have a cooling effect. “South East Asia is developing rapidly in economic terms,” Markus Rex explains a problem given little attention to date. “Contrary to most industrial nations, however, little has been invested in filter technology up to now. That is why sulphur dioxide emissions are increasing substantially in this region at present.”

This is how air reaches the stratosphere. Through the rapid
upward transport in tropical thunderstorms they reach an area
of slow large-scale ascent and rise from there through the
tropopause into the stratosphere over the course of weeks.
This process is most pronounced during northern hemispheric
winter. Model calculations show that, during this season, this
process mainly takes place over the tropical West Pacific. Due
to the formation of cirrus (= ice) clouds in the extremely cold
tropical tropopause, a large portion of the water-soluble
chemical substances is removed from the air and cannot reach
the stratosphere. OH molecules transform water-insoluble into
water-soluble compounds. Hence, if the concentration of OH
molecules along the dotted transport pathways shown above
is high only few chemical compounds make it into the
stratosphere. Conversely, the lower the OH concentration is
along the transport pathways, the more chemical
compounds enter the stratosphere.
Graphics: Yves Nowak, Alfred Wegener Institute.

If one takes into account that sulphur dioxide may also reach the stratosphere via the OH hole over the tropical West Pacific, it quickly becomes obvious that the atmospheric elevator over the South Seas not only boosts ozone depletion, but may influence the climate of the entire Earth. In fact, the aerosol layer in the stratosphere, which is also composed of sulphur particles, seems to have become thicker in recent years. Researchers do not know yet whether there is a connection here.

But wouldn’t it be a stroke of luck if air pollutants from South East Asia were able to mitigate climate warming? “By no means,” Markus Rex vigorously shakes his head. “The OH hole over the South Seas is above all further evidence of how complex climate processes are. And we are still a long way off from being in a position to assess the consequences of increased sulphur input into the stratosphere. Therefore, we should make every effort to understand the processes in the atmosphere as best we can and avoid any form of conscious or unconscious manipulation that would have an unknown outcome.”

Background:

Why is there an OH hole over the West Pacific?
The air in the tropical West Pacific is extremely clean. Air masses in this area were transported across the expanse of the huge Pacific with the trade winds and for a long time no longer had contact with forests or other land ecosystems that produce innumerable short-lived hydrocarbons and release them into the air. Under these clean air conditions OH is formed from ozone through chemical transformation to a great degree. If there is hardly any ozone in the lower atmosphere (= troposphere), as is the case in the West Pacific, only little OH can be formed. The result is an OH hole.

The graph shows ozone profiles measured in three different
marine regions: the tropical Atlantic, the tropical West Pacific
and the West Pacific outside the tropics. The red curve clearly
shows that ozone is consistently very low up to an altitude of
15 kilometres over the tropical West Pacific. In the other
regions the ozone concentrations are in a range typical
for the troposphere.
Graphics: Markus Rex, Alfred Wegener Institute

Ozone, in turn, forms in the lower atmosphere only if there are sufficient nitrogen oxides there. Large amounts of nitrogen oxide compounds are produced in particular by intensive lightning over land.

However, the air masses in the tropical West Pacific were not exposed to any continental tropical storms for a very long time during their transport across the giant ocean. And the lightning activity in storms over the ocean is relatively small. At the same time the lifetime of atmospheric ozone is short due to the exceptionally warm and moist conditions in the tropical West Pacific. In this South Sea region the surface temperatures of the ocean are higher than anywhere else on our planet, which makes the air not only quite warm, but also quite moist.

The ozone is thus quickly lost, especially directly above the water. And due to the lack of nitrogen oxide compounds little ozone is subsequently formed. Rapid vertical mixing in the convection areas that exist everywhere over the warm ocean and in which the warm air rises takes care of the rest. Finally, there is no more ozone in the entire column of air in the troposphere. And without ozone (see above) the formation of OH is suppressed.

What impact does the OH hole over the West Pacific have?

The illustration shows the average lifetime of sulphur dioxide
and some brominated hydrocarbons for normal conditions
over the tropical Atlantic and for conditions of reduced
OH-concentrations over the tropical West Pacific.
Graphics: Markus Rex, Alfred Wegener Institute

The OH molecule is also called the detergent of the atmosphere. Nearly all of the thousands of different chemical substances produced by people, animals, plants, fungi, algae or microorganisms on the ground or in the oceans react quickly with OH and break down in this process. Therefore, virtually none of these substances rises into the stratosphere. In the area of the OH hole, however, a larger portion of this varied chemical mix can enter the stratosphere.

And local emissions may unfold a global impact, especially if they make it to the stratosphere. There they spread globally and can influence the composition of the air for many years – with far-reaching consequences for ozone chemistry, aerosol formation and climate.

Why wasn’t the OH hole discovered earlier?
The tropical West Pacific is one of the most remote regions on our planet. That is why extensive measurements of the air composition have yet to take place in this area. There is also a considerable gap in the otherwise dense network of global ozone measurement stations here. Even in the past measurements from the peripheral sections of the now investigated region showed minimal ozone values in the area of the upper troposphere, but not the consistently low values that have now been found across the entire depth of the troposphere. The newly discovered phenomenon reveals itself in its full scope only through the measurements that were conducted to such an extensive degree for the first time and was thus not able to be grasped at all previously.

*One part of ozone per billion by volume (ppbv) means there is one ozone molecule for every billion air molecules.



Press release from the Alfred Wegener Institute, which conducts research in the Arctic, Antarctic and oceans of the high and mid-latitudes. It coordinates polar research in Germany and provides major infrastructure to the international scientific community, such as the research icebreaker Polarstern and stations in the Arctic and Antarctica. The Alfred Wegener Institute is one of the 18 research centres of the Helmholtz Association, the largest scientific organisation in Germany.

More on Wildfires

Previous posts have highlighted the huge amounts of carbon dioxide, methane and soot being emitted as a result of wildfires. Apart from this, there are further important pollutants to consider in regard to their potential to contribute to warming, especially at high latitudes.

The image below, dated August 7, 2013, and kindly supplied by Leonid Yurganov, shows high levels of carbon monoxide as a result of wildfires in Siberia, reaching high up into the Arctic all the way to Greenland. 

[ click on image to enlarge ]

Formation of tropospheric ozone mostly occurs when nitrogen oxides (NOx), carbon monoxide (CO) and volatile organic compounds (VOCs) react in the atmosphere in the presence of sunlight. NOx, CO, and VOCs are therefore called ozone precursors. Apart from a health hazard, tropospheric ozone is an important greenhouse gas. Furthermore, carbon monoxide emissions contribute to hydroxyl depletion, thus extending the lifetime of methane.

While there appears to be little or no carbon dioxide from wildfires over North America on the above August 7 image, there are many recent wildfires raging over the North American continent, as illustrated by the August 12 map below, from Wunderground. 

[ click on image to enlarge ]

This point is illustrated even better on the image below [added later, ed.] showing a composite image with carbon monoxide over July 3-13, 2013. Carbon monoxide resulting from wildfires in Canada is seen crossing the Atlantic Ocean, due to the Coriolis effect, as well as reaching Greenland in large amounts.

[ click on image to enlarge ]

Related

- Wildfires even more damaging
http://arctic-news.blogspot.com/2013/07/wildfires-even-more-damaging.html

- The Threat of Wildfires in the North
http://arctic-news.blogspot.com/2013/06/the-threat-of-wildfires-in-the-north.html

- Wildfires in Canada affect the Arctic
http://arctic-news.blogspot.com/2013/07/wildfires-in-canada-affect-the-arctic.html